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A-LevelChemistryHydroxy compounds9701/42 · Oct/Nov 2021 · Q105 Marks

Complete the table to show the structure of the organic product from each reaction of phenol, C₆H₅OH. [Figure not explicitly referenced, but implied by reaction table]

  1. (a)Complete the table to show the structure of the organic product from each reaction of phenol, C₆H₅OH. reaction reaction mixture structure of organic product 1 phenol + NaOH(aq) 2 phenol + Na(s) 3 phenol + [Figure N=N with benzene rings] + NaOH, at 4°C 4 an excess of phenol + [Figure benzene ring with meta-COCl and -COCl] [4]
  2. (b)Identify two reactions from the table in which ethanol would behave in a similar way to phenol.[1]

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Mark scheme

Marking points from the official mark scheme (Oct/Nov 2021). The mark or mark type is shown in brackets.

  1. [1] C₆H₅O⁻/C₆H₅O⁻Na⁺ / C₆H₅ONa
  2. [1] C₆H₅O⁻/C₆H₅O⁻Na⁺ / C₆H₅ONa
  3. [1] C₆H₅N₂C₆H₄O⁻ or C₆H₅N₂C₆H₄OH or [diagram of azo dye]
  4. [1] C₆H₅OCOC₆H₄CO₂C₆H₅
  5. [1] 2 and 4

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About this question

Topic
Hydroxy compounds, A-Level Chemistry (syllabus 9701). Structured question, 5 marks.
Source
A-Level Chemistry, Oct/Nov 2021 Paper 4 Variant 2, question 10.

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