The reaction scheme shows some reactions of calcium. [Figure 2.0]
- (a)(i)Reaction 1 produces Ca(NO3)2 and one other product. Identify the other product.[1]
- (a)(ii)Construct an equation for the thermal decomposition of Ca(NO3)2(s).[1]
- (a)(iii)State the trend in the thermal stability of the Group 2 nitrates down the group.[1]
- (a)(iv)In reaction 3, excess CO₂ is bubbled through water containing CaCO3. A solution of Ca(HCO3)2(aq) forms. Construct an equation for reaction 3.[1]
- (b)Describe how Ca(OH)2 is used in agriculture.[1]
- (c)(i)Describe how sp hybridised orbitals are formed.[1]
- (c)(ii)Sketch a diagram to show how two sp hybrid orbitals can form a sigma (σ) bond.[2]
- (d)(i)Reaction 5 can be used to prepare NH3. CaCN2 + 3H2O → CaCO3 + 2NH3 Calculate the minimum mass, in tonnes, of calcium cyanamide, CaCN2, that is required to produce 1.50 × 10⁶ tonnes of NH3. Show your working. 1 tonne = 1.00 × 10⁶g minimum mass of CaCN2 = ................................ tonnes[2]
- (d)(ii)Draw the structure of the organic products formed in the following reactions. [Figure 2.1][3]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2021). The mark or mark type is shown in brackets.
- [1] hydrogen / H2
- [1] Ca(NO3)2 → CaO + 2NO2 + 1/2O2
- [1] (thermal stability) increases
- [1] CaCO3 + H2O + CO2 → Ca(HCO3)2
- [1] reduces acidity of soil
- [1] Mixing / overlap / combination of one / an s and one / a p orbital
- [2] M1 (diagram showing two sp orbitals overlapping end-on) M2 (diagram showing sp-sp sigma bond)
- [2] M1 moles of NH3 = 1.50 × 106 × 106 ÷ 17 = 8.82 × 1010 M2 mass of CaCN2 = (1×M1×80.1) / 106 = 3.53 x 106
- [3] CH3CH2CN CH3CH2CO2H CH3C(OH)(CN)CH3
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