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A-LevelChemistryEquilibria9701/42 · Oct/Nov 2020 · Q26 Marks

Write an expression for the Ka of the weak acid HA in terms of the concentrations of the species involved. Ka =

  1. (a)Write an expression for the Ka of the weak acid HA in terms of the concentrations of the species involved. Ka =[1]
  2. (b)The hydroxylammonium ion, HONH3+, is a weak acid. A 1.00 × 10⁻³moldm⁻³ solution of hydroxylammonium ions has a pH of 4.41.
  3. (b)(i)Calculate the Ka of HONH3+. Ka =[2]
  4. (b)(ii)Calculate the pKa of HONH3+. pKa =[1]
  5. (c)The solubility product of manganese(II) hydroxide, Mn(OH)2, in water is 1.1 × 10⁻¹¹ mol³ dm-⁹ at 298 K. Calculate the solubility of Mn(OH)2 in water at 298 K. solubility =[2]

Mark scheme

Marking points from the official mark scheme (Oct/Nov 2020). The mark or mark type is shown in brackets.

  1. [1] [H+][A-]/ [HA]
  2. [1] [H+] = 3.9 × 10-5
  3. [1] Ka = 1.5 × 10-6
  4. [1] 5.82
  5. [1] 4 x³ = 1.1 × 10-11
  6. [1] x = 1.4 x 10-4

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About this question

Topic
Equilibria, A-Level Chemistry (syllabus 9701). Structured question, 6 marks.
Source
A-Level Chemistry, Oct/Nov 2020 Paper 4 Variant 2, question 2.

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