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A-LevelChemistryChemical periodicity9701/22 · Oct/Nov 2020 · Q214 Marks

The Period 3 elements, Na to S, all react with oxygen to form oxides.

  1. (a)State the trend in acid/base behaviour of the oxides of the Period 3 elements, from Na to S.[1]
  2. (b)State and explain the trend, from Na to S, in the maximum oxidation number of the Period 3 elements in their oxides.[2]
  3. (c)Sodium oxide and phosphorus(V) oxide both react with water. Name the product of each reaction. [Table with 'reaction' and 'product'][2]
  4. (d)Explain why phosphorus(V) oxide has a low melting point of approximately 300°C but magnesium oxide has a high melting point of approximately 2850 °C.[3]
  5. (e)Aluminium oxide, Al2O3, reacts separately with both acids and alkalis.
  6. (e)(i)Write an equation for the reaction of aluminium oxide with excess aqueous hydrochloric acid.[1]
  7. (e)(ii)Write an equation for the reaction of aluminium oxide with excess aqueous sodium hydroxide.[1]
  8. (f)Describe the lattice structure of silicon(IV) oxide. Your answer should include reference to the arrangement of the silicon and oxygen atoms and the bonds between them.[2]
  9. (g)Sodium oxide and silicon(IV) oxide react to form sodium silicate(IV), Na2SiO3. Sodium oxide is obtained from the thermal decomposition of sodium carbonate. Write equations for the following reactions:
  10. (g)(i)sodium oxide with silicon(IV) oxide[1]
  11. (g)(ii)the thermal decomposition of sodium carbonate, forming sodium oxide and carbon dioxide.[1]

Mark scheme

Marking points from the official mark scheme (Oct/Nov 2020). The mark or mark type is shown in brackets.

  1. [1] more acidic/less basic (from Na to S across period)
  2. [2] M1: increases (from Na to S/ across period) M2: increasing (number of) valence electrons OR (number of) electrons in outer (electron) shell increases
  3. [2] reaction name of product sodium oxide with water sodium hydroxide phosphorus(V) oxide with water phosphoric(V) acid
  4. [3] M1: identification of forces broken during melting of phosphorus(V) oxide intermolecular forces in phosphorus(V) oxide (are broken) M2: identification of force broken during melting of magnesium oxide electrostatic forces of attraction between (many oppositely charged) ions in magnesium oxide M3: statement linking difference in strength of appropriate forces described in M1& M2 to explain difference in melting point (only) intermolecular forces weaker than forces (of attraction) between ions / ionic bonds
  5. [1] Al2O3 + 6HCl → 2AlCl3 + 3H2O
  6. [1] Al2O3 + 2NaOH + 3H2O → 2NaAl(OH)4
  7. [2] M1: giant M2: covalent AND tetrahedral / four Si–O bonds
  8. [1] Na2O + SiO2 → Na2SiO3
  9. [1] Na2CO3 → Na2O + CO2

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About this question

Topic
Chemical periodicity, A-Level Chemistry (syllabus 9701). Structured question, 14 marks.
Source
A-Level Chemistry, Oct/Nov 2020 Paper 2 Variant 2, question 2.

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