A polymer, P, can be made from the monomers benzene-1,4-dioyl chloride and benzene-1,3-diamine. Benzene-1,4-dioyl chloride has structure with a benzene ring, two -COCl groups attached at positions 1 and 4. Benzene-1,3-diamine has structure with a benzene ring, two -NH2 groups attached at positions 1 and 3.
- (a)(i)Draw a section of the polymer chain of P. Your structure should include two repeat units. P[2]
- (a)(ii)Place one tick in the table to describe polymer P and its method of polymerisation. type of polymer | type of polymerisation | addition | condensation polyalkene polyamide polyester[1]
- (a)(iii)State whether or not polymer P is biodegradable. Give a reason for your answer.[1]
- (a)(iv)State a suitable reagent to produce benzene-1,4-dioyl chloride from benzene-1,4-dicarboxylic acid.[1]
- (a)(v)Benzene-1,3-diamine can be made from benzene using the reaction sequence shown. Step 1: Benzene to O₂N-C₆H₄-NO₂. Step 2: O₂N-C₆H₄-NO₂ to O₂N-C₆H₄-NH₂. Step 3: O₂N-C₆H₄-NH₂ to H₂N-C₆H₄-NH₂. State the reagents used for steps 1 and 3. step 1 step 3[2]
- (b)(i)Describe what is meant by each of these terms. primary structure secondary structure tertiary structure[3]
- (b)(ii)Name the forces or bonds responsible for holding together the primary structure of a protein molecule.[1]
- (b)(iii)Name the forces or bonds responsible for the stabilisation of the secondary structure of a protein molecule, and identify the groups of atoms within the protein molecule that are held together by these forces or bonds.[2]
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Mark scheme
Marking points from the official mark scheme (Oct/Nov 2019). The mark or mark type is shown in brackets.
- [2] • two or more repeat units
- [2] • correct orientation of groups on all four rings and rings correct
- [2] • trailing bonds shown
- [2] • amide links all correct
- [2] Award 1 mark for two points, award 2 marks for all four points
- [1] polyamide and condensation
- [1] yes and can be hydrolysed
- [1] PC13 or PC15 or SOC12
- [2] M1: conc nitric acid + conc sulfuric acid
- [2] M2: Sn + HCl
- [3] M1: sequence / order of amino acids
- [3] M2: a-helix or ẞ-sheet
- [3] M3: folding of chain or 3-D shape
- [1] covalent bonds / peptide bonds / amide bonds
- [2] M1: hydrogen bonds
- [2] M2: between C=O and N-H
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