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A-LevelChemistryNitrogen and sulfur9701/21 · Oct/Nov 2018 · Q215 Marks

Nitrogen, N2, is an inert gas that makes up 78% of the Earth's atmosphere. Explain why nitrogen is inert.

  1. (a)(i)Nitrogen, N2, is an inert gas that makes up 78% of the Earth's atmosphere. Explain why nitrogen is inert.[2]
  2. (a)(ii)Draw a 'dot-and-cross' diagram of a nitrogen molecule. Show outer electrons only.[1]
  3. (b)(i)Nitrogen, N2, and oxygen, O2, react together in the air during lightning strikes to form nitrogen monoxide, NO. Explain why the reaction of N2 and O2 occurs during lightning strikes.[1]
  4. (b)(ii)Write two equations to suggest how the NO formed reacts further to create nitric acid, HNO3. 1 2[2]
  5. (c)Nitrate fertilisers are used to provide nitrogen for plant growth. Uncontrolled use of these can cause a reduction in animal and plant life in natural water supplies. Explain how uncontrolled use of nitrate fertilisers can cause this problem.[3]
  6. (d)(i)Some soils have compounds such as ammonium nitrate, calcium carbonate and calcium hydroxide added to them. Suggest why calcium hydroxide is added to some soils.[1]
  7. (d)(ii)When calcium hydroxide reacts with compounds containing the ammonium ion, NH4+, a gas is produced. State the identity of this gas and explain why the reaction occurs. gas explanation[2]
  8. (d)(iii)Another fertiliser, calcium ammonium nitrate, is formed when solid calcium carbonate is added to a mixture of aqueous ammonium nitrate and dilute nitric acid. Suggest what would be observed in this reaction.[2]
  9. (d)(iv)Calcium nitrate decomposes at a higher temperature than calcium ammonium nitrate. Write an equation for the thermal decomposition of calcium nitrate.[1]

This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.

Mark scheme

Marking points from the official mark scheme (Oct/Nov 2018). The mark or mark type is shown in brackets.

  1. [2] 1 mark for each bullet, max 2: • triple bond; • non-polar / no dipole; • needs a lot of energy to break / strong
  2. [1] 6 e- between atoms AND two electrons on each N atom
  3. [1] (lightning) provides the (high) activation energy
  4. [2] M1 NO + ½ O2 → NO2; M2 2NO2 + H2O + ½ O2 → 2HNO3
  5. [3] M1 fertiliser / nitrates dissolve in (river / ground water) OR fertiliser / nitrates are washed / leached out / flows into (river/groundwater); M2 algal bloom / promote algal growth / explosion of plant growth AND sunlight is blocked out (preventing photosynthesis) / plants can no longer carry out photosynthesis (and die) AND bacteria break down or decay dead organisms / plants / algae; M3 drop in oxygen (concentration)
  6. [1] to increase / raise pH
  7. [2] M1 ammonia / NH3; M2 displaces NH3
  8. [2] M1 effervescence / fizzing / bubbling; M2 solid disappears
  9. [1] 2Ca(NO3)2 → 2CaO + 4NO2 + O2

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About this question

Topic
Nitrogen and sulfur, A-Level Chemistry (syllabus 9701). Structured question, 15 marks.
Source
A-Level Chemistry, Oct/Nov 2018 Paper 2 Variant 1, question 2.

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