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A-LevelChemistryCarboxylic acids and derivatives9701/41 · May/June 2025 · Q107 Marks

Propanoic acid, methanoic acid and ethanedioic acid are all weak acids.

  1. (a)Draw the displayed formula of ethanedioic acid.[1]
  2. (b)The three acids, propanoic acid, methanoic acid and ethanedioic acid, can be distinguished using a combination of two chemical tests. Neither testing reagent is an acid-base indicator. Identify two suitable testing reagents and complete Table 10.1 to show the observations from each test. reagent 1 ...................................................... reagent 2 ...................................................... Table 10.1 observation when treated with reagent 1 observation when treated with reagent 2 propanoic acid methanoic acid ethanedioic acid[4]
  3. (c)When propanoic acid is treated with chlorine gas in the presence of ultraviolet light, a mixture of products is formed. One of these products is 2,2-dichloropropanoic acid. Explain why 2,2-dichloropropanoic acid is stronger than propanoic acid. Refer to the structure of each compound in your answer.[2]

Mark scheme

Marking points from the official mark scheme (May/June 2025). The mark or mark type is shown in brackets.

  1. [1] HOOC-COOH (displayed formula)
  2. [4] M1: reagent 1:Fehling's OR Tollens' reagent
  3. [4] M2: acidified MnO4⁻
  4. [4] M3/M4: One completely correct column [1] both completely correct columns [2]

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About this question

Topic
Carboxylic acids and derivatives, A-Level Chemistry (syllabus 9701). Structured question, 7 marks.
Source
A-Level Chemistry, May/June 2025 Paper 4 Variant 1, question 10.

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