Diamond and graphite are both crystalline solids made from carbon atoms. Graphite conducts electricity. Diamond does not conduct electricity.
- (a)(i)Name the type of lattice structure present in the crystalline solids diamond and graphite.[1]
- (a)(ii)Explain how graphite conducts electricity.[1]
- (a)(iii)Explain why diamond does not conduct electricity.[1]
- (b)(i)Separate samples of phosphorus(V) chloride and silicon(IV) chloride are each added to an excess of cold water. Write an equation for each reaction.[2]
- (b)(ii)Describe the appearance of phosphorus(V) chloride and silicon(IV) chloride at room temperature. phosphorus(V) chloride silicon(IV) chloride[2]
- (b)(iii)Compare the appearance of the mixtures produced when each reaction is complete.[2]
- (c)(i)Some oxides are amphoteric. Describe what is meant by amphoteric.[1]
- (c)(ii)Identify the formula of a Period 3 oxide that is amphoteric.[1]
- (d)(i)The melting points of different oxides are shown in Table 1.1. Table 1.1 oxide | melting point/°C | force of attraction broken during melting SO2 | -73 | H2O | 0 | SiO2 | 1610 | Na2O | 1132 | MgO | 2852 | Complete Table 1.1 by identifying the strongest force of attraction in each oxide that is broken during melting. Use the abbreviations below. i.d. = instantaneous dipole-induced dipole p.d. = permanent dipole-permanent dipole H = hydrogen bond C = covalent bond I = ionic bond[3]
- (d)(ii)A student suggests the following hypothesis. The stronger the covalent bond between atoms in non-metal oxides, the higher the melting point. Use Table 1.1 to deduce if this hypothesis is true or false or if there is not enough information to make a conclusion. Explain your answer.[2]
Mark scheme
Marking points from the official mark scheme (May/June 2025). The mark or mark type is shown in brackets.
- 1(a)(i) (both) giant molecular
- 1(a)(ii) delocalised electrons move through the structure OR delocalised electrons move through / between the layers
- 1(a)(iii) no delocalised electrons (to carry charge through the structure) OR all (4) outer electrons are used in bonding
- 1(b)(i) PC15 +4H2O → H3PO4 + 5HCl
- 1(b)(i) SiCl4 + 2H2O → SiO2 + 4HCl
- 1(b)(ii) M1 phosphorus(V) chloride white / yellow solid
- 1(b)(ii) M2 silicon(IV) chloride colourless liquid
- 1(b)(iii) M1 (phosphorus(V) chloride) produces colourless solution
- 1(b)(iii) M2 silicon(IV) chloride produces white suspension / white precipitate (in a colorless liquid / mixture / solution)
- 1(c)(i) species behaves as acid and base OR species reacts with (both) acid and base
- 1(c)(ii) Al2O3
- 1(d)(i) SO2 -73 pd
- 1(d)(i) H2O 0 H
- 1(d)(i) SiO2 1600 C
- 1(d)(i) Na2O 1132 I
- 1(d)(i) MgO 2852 I
- 1(d)(ii) M1 not enough information
- 1(d)(ii) M2 SO2 and / or H2O break intermolecular forces OR SO2 and / or H2O does not break covalent bonds OR only SiO2 breaks covalent bonds
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