Fig. 1.1 shows the variation in melting point of some Period 3 elements in their standard states at room temperature and pressure.
- (a)Complete Table 1.1 using relevant information from the Periodic Table. Table 1.1 nucleon number proton number number of electrons Mg2+ 24 Al3+ 27[2]
- (b)State and explain the difference in the ionic radius of Al3+ compared to Mg2+.[3]
- (c)Draw a labelled diagram to show the structure and bonding in sodium.[1]
- (d)(i)Explain why Si has a high melting point.[1]
- (d)(ii)Complete Fig. 1.1 to show the variation in the melting points of the elements P, S and Cl.[2]
- (e)(i)Two Period 3 elements react with an excess of oxygen at room pressure. Complete Table 1.2. Table 1.2 1 Period 3 element 2 state of oxide at room temperature and pressure Na S 3 approximate pH of solution made when oxide is added to water[2]
- (e)(ii)The solutions made in column 3 of Table 1.2 are mixed together. Name the type of reaction that occurs.[1]
- (e)(iii)Write an equation to describe the reaction between P4O10 and an excess of water.[1]
- (f)(i)Aluminium hydroxide is amphoteric. Explain what is meant by amphoteric.[1]
- (f)(ii)Write an equation to describe the reaction that occurs when aluminium hydroxide, Al(OH)3, reacts with NaOH(aq).[1]
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Mark scheme
Marking points from the official mark scheme (May/June 2024). The mark or mark type is shown in brackets.
- [2] (a) Mg2+: proton number 12, number of electrons 10; Al3+: proton number 13, number of electrons 10 (4 correct = 2 marks, 2 or 3 correct = 1 mark)
- [1] (b) it/Al3+ is smaller (compared to Mg2+)
- [1] (b) greater nuclear attraction for remaining electrons
- [1] (b) same shielding effect AND greater nuclear charge
- [1] (c) labelled diagram shows: regular arrangement of minimum of 2 × 2 circles containing + for positive ions AND surrounded by (sea of) delocalised electrons
- [1] (d)(i) large amount of energy required to break bonds in giant covalent structure
- [1] (d)(ii) all 3 melting points lower than Mg
- [1] (d)(ii) show melting point Cl < P < S
- [2] (e)(i) Na oxide state: solid, pH: 10–14; S oxide state: gas, pH: 0–4 (4 correct = 2 marks, 2 or 3 correct = 1 mark)
- [1] (e)(ii) acid-base OR neutralisation
- [1] (e)(iii) P4O10 + 6H2O → 4H3PO4
- [1] (f)(i) reacts with both acids and bases OR shows both acidic and basic behaviour
- [1] (f)(ii) Al(OH)3 + NaOH → NaAl(OH)4
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