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A-LevelChemistryIntroduction to organic chemistry9701/41 · May/June 2023 · Q610 Marks

Compound H has the structural formula CH2=CHCH(NH2)COOH. Name all the functional groups in H.

  1. (a)(i)Compound H has the structural formula CH2=CHCH(NH2)COOH. Name all the functional groups in H.[2]
  2. (a)(ii)Compound H exhibits stereoisomerism. Draw three-dimensional structures for the two stereoisomers of H. Name this type of stereoisomerism.[2]
  3. (b)(i)Compound H can be prepared from the reaction of J with an excess of hot aqueous acid. [Figure 6.1] Complete Fig. 6.2 to show the equation for this reaction. [Figure 6.2][1]
  4. (b)(ii)Name the type of reaction in (b)(i).[1]
  5. (c)(i)Polymers consist of monomers joined together by undergoing either addition or condensation polymerisation. Compound H can react to form an addition polymer, K, or a condensation polymer, L, depending on the conditions. Draw one repeat unit of addition polymer K.[1]
  6. (c)(ii)Draw two repeat units of condensation polymer L. The new functional group formed should be displayed.[2]
  7. (c)(iii)Explain why condensation polymers can normally biodegrade more readily than addition polymers.[1]

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Mark scheme

Marking points from the official mark scheme (May/June 2023). The mark or mark type is shown in brackets.

  1. [2] carboxylic acid, amine, alkene Two correct for one mark, three correct for two marks
  2. [2] (drawings of stereoisomers) optical
  3. [1] (equation for hydrolysis)
  4. [1] hydrolysis
  5. [1] (repeat unit of addition polymer K)
  6. [2] M1 amide linkage displayed correctly
  7. [2] M2 rest of the structure correct
  8. [1] condensation polymers can be hydrolysed

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About this question

Topic
Introduction to organic chemistry, A-Level Chemistry (syllabus 9701). Structured question, 10 marks.
Source
A-Level Chemistry, May/June 2023 Paper 4 Variant 1, question 6.

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