Fig. 3.1 describes a sequence of reactions that can be used to produce a food additive, compound Y, from CH3CH2Cl. X step 1 step 2 step 3 CH3CH2Cl CH3CH2CN CH3CH2COOH Y dilute acid Ca(s) Fig. 3.1
- (a)(i)State the reagent and conditions for step 1 in Fig. 3.1.[1]
- (a)(ii)Give the systematic name of X.[1]
- (a)(iii)Identify the type of reaction that occurs when dilute acid is added to X in step 2.[1]
- (a)(iv)In step 3, Y and a gas are produced. Construct an equation for step 3.[2]
- (b)CH3CH2COOH can also be formed from propan-1-ol and potassium dichromate(VI). State the conditions required.[1]
- (c)Complete Table 3.1 to show the number of sigma bonds (σ) and pi bonds (π) present in a molecule of X. Table 3.1 type of bond | number of bonds in X ---|--- sigma (σ) | pi (π) |[2]
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Mark scheme
Marking points from the official mark scheme (May/June 2023). The mark or mark type is shown in brackets.
- [1] KCN in ethanol + heat
- [1] propanenitrile
- [1] (acid) hydrolysis
- [2] 2 CH3CH2COOH + Ca → (CH3CH2COO)2Ca + H2 M1 H2 as product M2 balanced equation based on correct formula of Y
- [1] acid (conditions) / H+(aq) AND heat under reflux
- [2] type of bond in X | number of bonds in X ---|--- sigma σ | 8 pi π | 2
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