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A-LevelChemistryNitrogen and sulfur9701/21 · May/June 2022 · Q212 Marks

Nitrogen molecules, N₂(g), contain two atoms attracted to each other by a triple covalent bond.

  1. (a)Describe how the triple covalent bond forms in a N₂(g) molecule. Refer to orbital overlap and hybridisation in your answer.[3]
  2. (b)(i)Outline how nitrogen oxides are involved in the formation of photochemical smog.[2]
  3. (b)(ii)Construct an equation to demonstrate how a catalytic converter reduces the amount of nitrogen oxide gases released into the atmosphere.[1]
  4. (c)N₂(g) is very unreactive. It is difficult to make ammonia, NH₃(g), directly from its elements but it can be made from NH₄Cl(s). Identify a reagent and the conditions required to make NH₃(g) from NH₄Cl(s).[1]
  5. (d)(i)Describe what is meant by a strong Brønsted-Lowry acid.[2]
  6. (d)(ii)NH₃ is a weak base. Construct an equation that shows the behaviour of NH₃ as a weak Brønsted-Lowry base when dissolved in water.[1]
  7. (d)(iii)On Fig. 2.1 sketch a graph to show the change in pH which occurs when HCl(aq) is titrated with NH₃(aq) as described in (d).[2]

This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.

Mark scheme

Marking points from the official mark scheme (May/June 2022). The mark or mark type is shown in brackets.

  1. [3] M1 one sigma / σ bond and two pi / π bonds
  2. [3] M2 sp hybridisation (in each N atom)
  3. [3] M3 sigma / σ forms from direct / head-on / end-on overlap of orbitals AND pi / π forms sideways / lateral overlap of (p) orbitals
  4. [2] M1 react with (unburnt) hydrocarbons
  5. [2] M2 (form) PAN / peroxyac(et)yl nitrate
  6. [1] 2NO + 2CO → 2CO2 + N2 OR NO2 + 2CO → ½N2 + 2CO2
  7. [1] any Group 1 hydroxide or Ca(OH)2 / Sr(OH)2 / Ba(OH)2
  8. [2] M1 proton / H+ donor
  9. [2] M2 fully dissociates (in aqueous solution / water / solvent)
  10. [1] NH3 + H2O ⇌ NH4+ + OH-
  11. [2] M1 correct basic shape extending to ~50cm³ with vertical portion of curve at 25 cm³
  12. [2] M2 initial pH at 0–2 (based on idea that HCl is a strong acid) AND final pH at between 8-12 (based on idea that NH3 is a weak alkali)

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About this question

Topic
Nitrogen and sulfur, A-Level Chemistry (syllabus 9701). Structured question, 12 marks.
Source
A-Level Chemistry, May/June 2022 Paper 2 Variant 1, question 2.

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