The strength of interaction between particles determines whether the substance is a solid, liquid or gas at room temperature.
- (a)(i)Lithium sulfide, Li₂S, is a crystalline solid with a melting point of 938°C. It conducts electricity when it is molten. Give the formulae of the particles present in solid lithium sulfide.[1]
- (a)(ii)Explain, in terms of the structure of the crystalline solid, why lithium sulfide has a high melting point.[2]
- (b)(i)Carbon monoxide, CO, is a gas at room temperature and pressure. It contains a coordinate bond. Explain what is meant by coordinate bond.[1]
- (b)(ii)Draw a 'dot-and-cross' diagram to show the arrangement of outer electrons in CO. Show the electrons belonging to the C atom as x. Show the electrons belonging to the O atom as •.[2]
- (c)(i)Nitrogen, N2, is also a gas at room temperature and pressure. Neither CO nor N₂ is an ideal gas. State two assumptions that are made about the behaviour of particles in an ideal gas. 1 2[2]
- (c)(ii)Explain why N₂ does not behave as an ideal gas at very high pressures.[2]
- (c)(iii)Complete the table by naming all the types of intermolecular forces (van der Waals') in separate samples of N₂(g) and CO(g). [Table with N2(g) and CO(g) data for electrons, dipole moment, boiling point, and blank row for intermolecular forces] number of electrons per molecule N2(g) 14 CO(g) 14 presence of a dipole moment X ✓ boiling point/°C -195.8 -191.5 intermolecular forces (van der Waals')[2]
- (c)(iv)Suggest why the bond in a molecule of CO contains a dipole moment.[1]
This question uses a diagram from the original paper, which isn't shown here. Open the full paper from the past papers archive to see it.
Mark scheme
Marking points from the official mark scheme (May/June 2021). The mark or mark type is shown in brackets.
- [1] Li+ AND S2-
- [1] M1 giant
- [1] M2 (many) strong force(s) of attraction between oppositely charged ions OR (many) strong ionic bond(s)
- [1] (covalent) bond with both electrons are provided from the same / one species OR shared pair (of electrons) are provided from the same species / one atom owtte
- [2] 3 bonding pairs between C and O, 4 •'s AND 2x's 1 lone pair on C, ××, AND 1 lone pair on O, ••.
- [2] Any two assumptions about the behaviour of particles in an ideal gas from • (particles / molecules have mass but) negligible size / volume (compared to total volume of gas / container) • no / negligible forces / interactions (between particles / molecules) • collisions are elastic
- [1] M1 IMF become larger / more significant
- [1] M2 volume of molecules / particles becomes significant / no longer negligible
- [2] N2(g) instantaneous dipole-induced dipole ✓ CO(g) instantaneous dipole-induced dipole (and) permanent dipole-permanent dipole ✓
- [1] O is more electronegative than C
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