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A-LevelChemistryGroup 29701/22 · May/June 2021 · Q116 Marks

A Group 2 metal combines with bromine to form a crystalline solid, MBr2. Excess aqueous AgNO3 is added to a solution of MBr2 and a precipitate forms. The mixture is filtered. The precipitate is dried and the mass of the precipitate is recorded.

  1. (a)State the formula and colour of the precipitate.[2]
  2. (b)Complete the equation to represent the reaction between MBr2 and AgNO3. .MBr2 + ......AgNO3 → [1]
  3. (c)A 0.250 g sample of pure MBr₂ contains 8.415 × 10–4 mol MBr2. Calculate the relative formula mass, Mr, of MBr2. Use this to identify M. Show your working. M = M =[3]
  4. (d)(i)A sample of MBr2 is dissolved in water. Chlorine gas is then bubbled into the solution. Describe the observations for this reaction.[1]
  5. (d)(ii)Name the type of reaction that occurs when MBr₂ reacts with chlorine gas.[1]
  6. (e)Compound Y is a pure insoluble solid which contains halide ions. A single reagent is added directly to compound Y to determine the halide ion present. Identify the reagent added. State the observation which would confirm that Y contains bromide ions. reagent observation[2]
  7. (f)(i)Separate 1.0g samples of three different magnesium salts are tested in order to identify the anion present in each sample. Explain how the action of heat is used to identify which sample is: • MgCO3 • Mg(NO3)2 • MgO.[3]
  8. (f)(ii)Complete the electron configuration of the magnesium cation present in these salts. 1s2[1]
  9. (g)A sample of MgCO3(s) is distinguished from a sample of Mg(OH)2(s) by adding a small amount of each solid to HCl(aq). State one similarity and one difference in these two reactions. similarity difference[2]

Mark scheme

Marking points from the official mark scheme (May/June 2021). The mark or mark type is shown in brackets.

  1. [1] M1 cream
  2. [1] M2 AgBr
  3. [1] (1)MBr2 + 2AgNO3 → 2AgBr + M(NO3)2
  4. [1] M1 calculate Mr of MBr2 using 8.415 × 10–4 mol MBr2 in 0.250 g Mr = ....... = 297(.1).........
  5. [1] M2 calculate the atomic mass of M using Mr calculated in M1 297.1 – (2 × 79.9) = 137(.4)
  6. [1] M3 identify group 2 element from Arin M2 Ba/barium
  7. [1] (solution / mixture / liquid) turns (colourless to) orange or brown
  8. [1] displacement
  9. [1] M1 reagent: concentrated sulfuric acid
  10. [1] M2 observation: brown vapour/gas (forms)
  11. [1] explain how the action of heat is used to identify the 3 samples
  12. [1] M1 nitrate AND carbonate lose mass / less than 1 g
  13. [1] M2 nitrate produces brown (NO2) fumes
  14. [1] M3 MgO no reaction / MgO no change
  15. [1] electronic configuration of Mg2+ (1s²) 2s22p6
  16. [1] One similarity M1 solid(s) disappear(s)
  17. [1] One difference M2 MgCO3 fizzes (due to CO2) OR no fizzing with Mg(OH)2

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About this question

Topic
Group 2, A-Level Chemistry (syllabus 9701). Structured question, 16 marks.
Source
A-Level Chemistry, May/June 2021 Paper 2 Variant 2, question 1.

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