Complete the table by placing one tick (✔) in each row to indicate the sign of each type of energy change under standard conditions. [Table 6.a: energy change | always positive | always negative | either negative or positive bond energy | enthalpy change of formation |]
- (a)Complete the table by placing one tick (✔) in each row to indicate the sign of each type of energy change under standard conditions. [Table 6.a: energy change | always positive | always negative | either negative or positive bond energy | enthalpy change of formation |][1]
- (b)Explain what is meant by the term enthalpy change of atomisation.[1]
- (c)The overall reaction for the atomisation of liquid bromine molecules, Br₂(l), is shown. Br₂(l) → 2Br(g) This happens via a two-step process. • Construct a labelled energy cycle to represent this atomisation process, including state symbols. • Use your cycle and relevant data from the Data Booklet to calculate the enthalpy change of vaporisation of Br2(l), ∆H°vap. The enthalpy change of atomisation of bromine, ∆Hat, = +112kJmol⁻¹. ∆H°vap[3]
- (d)Suggest how the ∆H°vap of iodine, I2(l), would compare to that of bromine, Br₂(l). Explain your answer.[1]
- (e)(i)Explain what is meant by the term enthalpy change of hydration.[1]
- (e)(ii)Suggest why the enthalpy change of hydration of Br⁻(g) is more exothermic than that of I⁻(g).[2]
Mark scheme
Marking points from the official mark scheme (May/June 2019). The mark or mark type is shown in brackets.
- energy change: bond energy (always positive) / enthalpy of formation (either negative or positive) both ticks correct
- (energy change) when 1 mole of gaseous atoms are formed (from an element in its standard state)
- M1: correct cycle: formulae and state symbols
- M2: use of 1 x 193 and 2 x (112)
- M3: for the correct sum and answer ecf from M2 ∆Hvap (= (2 × 112) – (193) ) = +31 kJ mol−1 [scores M2 and M3]
- more endothermic and greater Van der Waals / London / induced dipole-dipole forces both
- (energy change) when 1 mole of gaseous ions is dissolved in (an excess of) water
- M1: Br has a smaller ionic radii
- M2: stronger (ion-dipole) attractions with water molecules
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