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Cambridge & Pearson Edexcel Past Paper Questions

Browse 35,704 questions from Cambridge O-Level & A-Level and Pearson Edexcel IGCSE & IAL exams. Click any question to practice.

A-LevelChemistryChemical bondingMay/June 2013

Which statement about ammonia is completely correct?

A-LevelChemistryGroup 17May/June 2013

What happens when bromine solution is added to a solution of sodium iodide?

A-LevelChemistryGroup 17May/June 2013

The halogens exist as diatomic molecules, X₂. The boiling points of the Group VII elements increase as the group is descended from chlorine to iodi...

A-LevelChemistryHydroxy compoundsMay/June 2013

The compound hex-3-en-1-ol, P, has a strong 'leafy' smell of newly cut grass and is used in perfumery. CH₃CH₂CH=CHCH₂CH₂OH P What is produced when ...

A-LevelChemistryHydrocarbonsMay/June 2013

Sorbic acid is used as a food preservative because it kills fungi and moulds. [Figure 21.1] Sorbic acid will react with • hydrogen in the presence ...

A-LevelChemistryHalogen derivativesMay/June 2013

Aqueous sodium hydroxide reacts with 2-bromo-2-methylpropane to give 2-methylpropan-2-ol. The reaction proceeds by an Sɴ1 mechanism. How should the...

A-LevelChemistryHalogen derivativesMay/June 2013

Compound Y can be hydrolysed by warm aqueous silver nitrate to form a precipitate that is soluble in dilute aqueous ammonia. Compound Y can undergo...

A-LevelChemistryHydroxy compoundsMay/June 2013

The compound shown is menthol, a naturally-occurring alcohol found in peppermint oil. [Figure 25.1] When menthol is heated with concentrated sulfur...

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2013

Use of the Data Booklet is relevant to this question. Which volume of oxygen measured at room temperature and pressure is needed for complete combu...

A-LevelChemistryCarbonyl compoundsMay/June 2013

Which carbonyl compound reacts with hydrogen cyanide to form a product that has no chiral carbon atom?

A-LevelChemistryOrganic synthesisMay/June 2013

How many of the following compounds produce a carboxylic acid on heating under reflux with hot acidified K₂Cr₂O₇? CH₃CH₂CHO CH₃COCH₃ CH₃CH₂CH₂OH CH...

A-LevelChemistryCarboxylic acids and derivativesMay/June 2013

Compound Y has Mᵣ of 88. It does not fizz when added to a solution of sodium hydrogencarbonate. It can be hydrolysed by dilute sulfuric acid to pro...

A-LevelChemistryPolymerisationMay/June 2013

Polymerisation of ethene gives poly(ethene). How does the carbon–carbon bond in poly(ethene) compare with that in ethene?

A-LevelChemistryAtomic structureMay/June 2013

Use of the Data Booklet is relevant to this question. In which pairs do both species have the same number of unpaired p electrons? 1 Al²⁻ and O⁺ 2 ...

A-LevelChemistryChemical energeticsMay/June 2013

The diagram shows the reaction pathway for a reversible reaction. [Figure 32.1] Which statements are correct? 1 The enthalpy change for the backwar...

A-LevelChemistryChemical bondingMay/June 2013

Which substances contain delocalised electrons? 1 cyclohexene 2 graphite 3 sodium

A-LevelChemistryGroup 2May/June 2013

Solids W, X, Y and Z are compounds of two different Group II metals. Some of their applications are described below. Compound W is used as a refrac...

A-LevelChemistryGroup 17May/June 2013

Which properties increase in the sequence hydrogen chloride, hydrogen bromide and hydrogen iodide? 1 thermal stability 2 bond length 3 ease of oxid...

A-LevelChemistryReaction kineticsMay/June 2013

Sulfur dioxide is an atmospheric pollutant that causes acid rain. One of the reactions in this process is the oxidation of sulfur dioxide to sulfur...

A-LevelChemistryHalogen derivativesMay/June 2013

Which are properties of fluoroalkanes? 1 They are less reactive than the corresponding chloroalkanes. 2 They are non-flammable. 3 The C–F bond is s...

A-LevelChemistryHydroxy compoundsMay/June 2013

What can be produced when an aqueous solution of butan-2-ol is oxidised under suitable conditions? 1 butanone 2 butanoic acid 3 butanal

A-LevelChemistryCarbonyl compoundsMay/June 2013

The Mᵣ of compound X is 72. The composition by mass of X is 66.7% carbon, 11.1% hydrogen and 22.2% oxygen. X gives an orange precipitate with 2,4-d...

A-LevelChemistryCarboxylic acids and derivativesMay/June 2013

An organic compound, Z, will react with calcium metal to produce a salt with the empirical formula CaC₄H₆O₄. What could be the identity of Z? 1 eth...

A-LevelChemistryReaction kineticsMay/June 2014

The diagram shows a Boltzmann distribution of molecular energies for a gaseous mixture. The distribution has a peak, labelled P on the diagram. [Fi...

A-LevelChemistryChemical bondingMay/June 2014

Substances X, Y and Z are all solids. Some of their physical properties are given in the table. [Figure 2.1] What type of lattice could each substa...

A-LevelChemistryChemical energeticsMay/June 2014

The enthalpy change of formation of carbon dioxide is –394 kJ mol⁻¹. The enthalpy change of formation of water is –286 kJ mol⁻¹. The enthalpy chang...

A-LevelChemistryEquilibriaMay/June 2014

Hydrogen and carbon dioxide gases are mixed in equal molar amounts at 800K. A reversible reaction takes place. H2(g) + CO2(g) ⇌ H2O(g) + CO(g) At e...

A-LevelChemistryReaction kineticsMay/June 2014

In the diagram, curve X was obtained by observing the decomposition of 100 cm³ of 1.0 mol dm⁻³ hydrogen peroxide, catalysed by manganese(IV) oxide....

A-LevelChemistryElectrochemistryMay/June 2014

In which reaction is the species in bold acting as an oxidising agent?

A-LevelChemistryEquilibriaMay/June 2014

The formation of hydrogen and ethyne, C2H2, from methane reaches dynamic equilibrium. 2CH4(g) ⇌ 3H2(g) + C2H2(g) What are the units of Kp?

A-LevelChemistryChemical energeticsMay/June 2014

Which equation represents the standard enthalpy change of formation of ethanol, C2H5OH?

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2014

Use of the Data Booklet is relevant to this question. In an experiment, 12.0 dm³ of oxygen, measured under room conditions, is used to burn complet...

A-LevelChemistryChemical periodicityMay/June 2014

Shown on the graph are the relative values of the first ionisation energies of four elements that have consecutive atomic numbers. One of the eleme...

A-LevelChemistryChemical energeticsMay/June 2014

The diagram shows the skeletal formula of cyclopropane. [Figure 11.1] The enthalpy change of formation of cyclopropane is +53.3 kJ mol⁻¹ and the en...

A-LevelChemistryGroup 2May/June 2014

When barium is burnt in oxygen, what colour is the flame?

A-LevelChemistryChemical periodicityMay/June 2014

X and Y are oxides of different Period 3 elements. If one mole of Y is added to water, the solution formed is neutralised by exactly one mole of X....

A-LevelChemistryNitrogen and sulfurMay/June 2014

Ammonium sulfate in the soil is slowly oxidised by air, producing sulfuric acid, nitric acid and water as the only products. How many moles of oxyg...

A-LevelChemistryGroup 2May/June 2014

Which statement about the oxides and hydroxides of the Group II elements Mg, Ca, Sr and Ba is correct?

A-LevelChemistryChemical periodicityMay/June 2014

Which graph correctly shows the relative melting points of the elements Mg, Al, Si and P plotted against their relative electronegativities? [Figur...

A-LevelChemistryElectrochemistryMay/June 2014

When solid sodium iodide reacts with concentrated sulfuric acid, the products include NaHSO4, H2S, SO2 and S. In the formation of which product has...

A-LevelChemistryGroup 17May/June 2014

A test-tube of HBr(g) and a test-tube of HI(g) are heated to the same temperature. Which combination of observations is possible? [Figure 18.1]

A-LevelChemistryAtoms, molecules and stoichiometryMay/June 2014

Use of the Data Booklet is relevant to this question. In an experiment, 0.125 mol of chlorine gas, Cl2, is reacted with an excess of cold aqueous s...

A-LevelChemistryIntroduction to organic chemistryMay/June 2014

The diagram shows the skeletal formula of phenazine. [Figure 20.1] What is the empirical formula of phenazine?

A-LevelChemistryHalogen derivativesMay/June 2014

Halogenoalkanes undergo a range of nucleophilic substitution reactions. Which reaction proceeds only by an SN1 mechanism?

A-LevelChemistryHydroxy compoundsMay/June 2014

Which alcohol has a chiral centre and can be oxidised to a ketone?

A-LevelChemistryCarboxylic acids and derivativesMay/June 2014

An ester of structural formula CH3CO2CH3 is heated with an aqueous solution of sodium hydroxide. What are the two organic products of this reaction?

A-LevelChemistryHalogen derivativesMay/June 2014

Ethene reacts with aqueous bromine to give two products, CH2BrCH2Br and CH2BrCH2OH. Which statement about these products is correct?

A-LevelChemistryPolymerisationMay/June 2014

Which statement does not correctly describe a problem related to the disposal of PVC?

A-LevelChemistryCarbonyl compoundsMay/June 2014

Compound X, C4H8O, produces an orange precipitate when it is reacted with 2,4-dinitrophenylhydrazine reagent. Compound X produces a carboxylic acid...

A-LevelChemistryHalogen derivativesMay/June 2014

Dichlorodifluoromethane, CCl2F2, has been used in aerosol propellants and as a refrigerant. Which statement helps to explain why dichlorodifluorome...

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