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A-LevelChemistryReaction kinetics9701/12 · May/June 2010 · Q131 Mark

Na2S2O3 reacts with dilute HCl to give a pale yellow precipitate. If 1 cm³ of 0.1 mol dm⁻³ HCl is added to 10 cm³ of 0.02 mol dm⁻³ Na2S2O3 the precipitate forms slowly. If the experiment is repeated with 1 cm³ of 0.1 mol dm⁻³ HCl and 10 cm³ of 0.05 mol dm⁻³ Na2S2O3 the precipitate forms more quickly. Why is this?

AThe activation energy of the reaction is lower when 0.05 mol dm⁻³ Na2S2O3 is used.
BThe reaction proceeds by a different pathway when 0.05 mol dm⁻³ Na2S2O3 is used.
CThe collisions between reactant particles are more violent when 0.05 mol dm⁻³ Na2S2O3 is used.
DThe reactant particles collide more frequently when 0.05 mol dm⁻³ Na2S2O3 is used.

✓ Correct answer

D: The reactant particles collide more frequently when 0.05 mol dm⁻³ Na2S2O3 is used.

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About this question

Topic
Reaction kinetics, A-Level Chemistry (syllabus 9701). Multiple choice, 1 mark.
Source
A-Level Chemistry, May/June 2010 Paper 1 Variant 2, question 13.

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