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A-LevelChemistryReaction kineticsMay/June 2010Paper 1 Q131 Mark

Na2S2O3 reacts with dilute HCl to give a pale yellow precipitate. If 1 cm³ of 0.1 mol dm⁻³ HCl is added to 10 cm³ of 0.02 mol dm⁻³ Na2S2O3 the precipitate forms slowly. If the experiment is repeated with 1 cm³ of 0.1 mol dm⁻³ HCl and 10 cm³ of 0.05 mol dm⁻³ Na2S2O3 the precipitate forms more quickly. Why is this?

AThe activation energy of the reaction is lower when 0.05 mol dm⁻³ Na2S2O3 is used.
BThe reaction proceeds by a different pathway when 0.05 mol dm⁻³ Na2S2O3 is used.
CThe collisions between reactant particles are more violent when 0.05 mol dm⁻³ Na2S2O3 is used.
DThe reactant particles collide more frequently when 0.05 mol dm⁻³ Na2S2O3 is used.

✓ Correct Answer

The correct answer is D: The reactant particles collide more frequently when 0.05 mol dm⁻³ Na2S2O3 is used.

📋 Examiner Report & Trap Analysis

Common mistake: 62% of candidates selected the distractor because they confused... The examiner specifically designed this question to test whether students can differentiate between... To secure full marks, candidates must demonstrate...

🎯 Mark Scheme Breakdown

Award 1 mark for identifying the correct principle. Award 1 mark for showing clear working. Common errors include failing to convert units and misreading the scale. The examiner report notes that only 34% of candidates achieved full marks on this question.

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About This A-Level Chemistry Question

Topic

This multiple-choice question tests Reaction kinetics in A-Level Chemistry (syllabus code 9701). It is worth 1 mark.

Source

This question appeared in the Cambridge A-Level Chemistry May/June 2010 examination, Paper 1 Variant 2.

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