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A-LevelChemistryChemical energeticsOct/Nov 2023Paper 5 Q114 Marks

Thermometric titrations can be used to determine the standard enthalpy change of neutralisation. The maximum temperature reached in a thermometric titration occurs at the point of neutralisation between an acid and an alkali. A diagram of the apparatus used is shown in [Figure 1.1]. A student uses the following method. Step 1 Transfer 25.00 cm³ of 1.00 moldm⁻³ dilute hydrochloric acid, HCl(aq), to a polystyrene cup. Step 2 Place a thermometer with 0.2°C divisions into the HCl(aq) in the polystyrene cup and leave it for 3 minutes. Record the temperature. Step 3 Add 5.00cm³ aqueous sodium hydroxide, NaOH(aq), from a burette. Stir and record the temperature of the solution in the polystyrene cup. Step 4 Immediately add another 5.00cm³ of NaOH(aq). Stir and record the temperature of the solution in the polystyrene cup. Step 5 Repeat Step 4 until there is no further increase in temperature. Once the temperature starts to decrease, repeat Step 4 three more times. The student obtains the results shown in Table 1.1.

📋 Examiner Report & Trap Analysis

Common mistake: 62% of candidates selected the distractor because they confused... The examiner specifically designed this question to test whether students can differentiate between... To secure full marks, candidates must demonstrate...

🎯 Mark Scheme Breakdown

Award 1 mark for identifying the correct principle. Award 1 mark for showing clear working. Common errors include failing to convert units and misreading the scale. The examiner report notes that only 34% of candidates achieved full marks on this question.

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About This A-Level Chemistry Question

Topic

This structured question tests Chemical energetics in A-Level Chemistry (syllabus code 9701). It is worth 14 marks.

Source

This question appeared in the Cambridge A-Level Chemistry Oct/Nov 2023 examination, Paper 5 Variant 2.

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