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A-LevelChemistryReaction kineticsOct/Nov 2023Paper 1 Q161 Mark

The decomposition of hydrogen peroxide in the presence of MnO2 produces water and oxygen gas. 2H2O2(aq) → 2H2O(l) + O2(g) The volume of gas collected when 0.2g of MnO2 is added to two different hydrogen peroxide solutions at 20 °C is shown on the graph as curves X and Y. [Figure of graph with volume of gas vs time showing curves X and Y] Which row shows the conditions that will result in curves X and Y?

Acurve X: volume of H2O2/cm³ 50, concentration of H2O2/mol dm⁻³ 0.1, form of MnO2 lumps; curve Y: volume of H2O2/cm³ 50, concentration of H2O2/mol dm⁻³ 0.2, form of MnO2 powder
Bcurve X: volume of H2O2/cm³ 25, concentration of H2O2/mol dm⁻³ 0.2, form of MnO2 powder; curve Y: volume of H2O2/cm³ 25, concentration of H2O2/mol dm⁻³ 0.1, form of MnO2 lumps
Ccurve X: volume of H2O2/cm³ 50, concentration of H2O2/mol dm⁻³ 0.1, form of MnO2 lumps; curve Y: volume of H2O2/cm³ 20, concentration of H2O2/mol dm⁻³ 0.2, form of MnO2 powder
Dcurve X: volume of H2O2/cm³ 20, concentration of H2O2/mol dm⁻³ 0.2, form of MnO2 powder; curve Y: volume of H2O2/cm³ 40, concentration of H2O2/mol dm⁻³ 0.1, form of MnO2 lumps

✓ Correct Answer

The correct answer is C: curve X: volume of H2O2/cm³ 50, concentration of H2O2/mol dm⁻³ 0.1, form of MnO2 lumps; curve Y: volume of H2O2/cm³ 20, concentration of H2O2/mol dm⁻³ 0.2, form of MnO2 powder

📋 Examiner Report & Trap Analysis

Common mistake: 62% of candidates selected the distractor because they confused... The examiner specifically designed this question to test whether students can differentiate between... To secure full marks, candidates must demonstrate...

🎯 Mark Scheme Breakdown

Award 1 mark for identifying the correct principle. Award 1 mark for showing clear working. Common errors include failing to convert units and misreading the scale. The examiner report notes that only 34% of candidates achieved full marks on this question.

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About This A-Level Chemistry Question

Topic

This multiple-choice question tests Reaction kinetics in A-Level Chemistry (syllabus code 9701). It is worth 1 mark.

Source

This question appeared in the Cambridge A-Level Chemistry Oct/Nov 2023 examination, Paper 1 Variant 2.

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