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A-LevelChemistryStates of matterOct/Nov 2022Paper 5 Q213 Marks

Charles' law states that for a fixed mass of gas at constant pressure, its volume is proportional to its absolute temperature. Most gases are non-ideal and do not obey this law, but at lower pressures and high temperatures some gases are close to ideal behaviour. One gas that behaves like this is oxygen. Oxygen can be prepared by decomposing hydrogen peroxide with the catalyst manganese(IV) oxide, MnO2. The equation for the decomposition of hydrogen peroxide is shown. 2H2O2(aq) → 2H2O(l) + O2(g) Safety hazard: hydrogen peroxide is corrosive to skin and can cause serious eye damage. gas syringe oxygen heat thermometer beaker water [Figure 2.1] Once the apparatus is assembled the volume of oxygen in the gas syringe is 2cm³. There are 80 cm³ of oxygen remaining in the flask. The total volume of oxygen is 82 cm³. Charles' law is investigated by the following method. step 1 Once assembled allow the apparatus to reach room temperature. step 2 Record this temperature and the total volume of oxygen reading on the syringe. step 3 Gently heat the apparatus until the temperature reaches 30 °C and record the total volume of oxygen. step 4 Repeat at intervals of 5°C until the temperature reaches 70°C. The student carried out the experiment and obtained the following results: Table 2.1 temperature /°C absolute temperature/K total volume of oxygen gas/cm³ 24 297 82 30 303 84 35 308 88 40 313 88 45 318 89 50 323 91 55 328 93 60 333 95 65 338 97 70 343 98

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About This A-Level Chemistry Question

This structured question appeared in the Cambridge A-Level Chemistry (9701) Oct/Nov 2022 examination, Paper 5 Variant 1. It tests the topic of States of matter and is worth 13 marks.

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