Pure water is a very poor conductor of electricity. However, when hydrogen chloride gas is dissolved in water, ions are formed and a current flows during electrolysis. HCl(g) + aq → H⁺(aq) + Cl⁻(aq) The overall change after electrolysis is that hydrogen chloride gas is converted into hydrogen and chlorine. 2HCl(g) → H₂(g) + Cl₂(g) When a current of 3.10A is passed through the solution for Y minutes, 351 cm³ of chlorine are produced at the anode, measured under room conditions.
- (a)Calculate the number of chlorine molecules produced during the electrolysis.[2]
- (b)Calculate the total number of electrons transferred to produce this number of chlorine molecules.[1]
- (c)Calculate the quantity of charge, in coulombs, of the total number of electrons calculated in (b).[1]
- (d)Calculate the time, Y, in minutes, for which the current flows.[1]
- (e)(i)The standard entropies, S°, of three species are given in the table. species S°/JK⁻¹ mol⁻¹ HCl(g) +187 H₂(g) +131 Cl₂(g) +223 Calculate ∆S° for the reaction 2HCl(g) → H₂(g) + Cl₂(g).[1]
- (e)(ii)∆H° for the reaction 2HCl(g) → H₂(g) + Cl₂(g) is +185kJmol⁻¹. Calculate ∆G° for this reaction at 298 K.[2]
- (e)(iii)Predict the effect of increasing temperature on the spontaneity of this reaction. Explain your answer.[1]
Mark scheme
Marking points from the official mark scheme (Oct/Nov 2021). The mark or mark type is shown in brackets.
- [1] 0.351 / 24 = 0.015 (mol)
- [1] 0.015 × 6.02 × 10²³ = 9.0 × 10²¹ / 8.8 × 10²¹
- [1] 1.76 x 10²² / 1.8 × 10²²
- [1] 2817/2816/2820 / 2800 C
- [1] 15/15.1/15.05 / 15.15 minutes
- [1] -20
- [1] states / uses correct Gibbs equation
- [1] answer = 190 / 191 / 190.0
- [1] Becomes less feasible / less spontaneous / AND because ∆S is negative / T∆S becomes more negative /-T∆S becomes more positive
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