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A-LevelChemistryGroup 17Oct/Nov 2020Paper 1 Q141 Mark

AgNO₃(aq) is added to a solution of a halide ion, X⁻(aq), and aqueous ammonia is then added. The ionic equations for the two reactions that occur are shown. Ag⁺(aq) + X⁻(aq) ⇌ AgX(s) equilibrium 1 Ag⁺(aq) + 2NH₃(aq) ⇌ Ag(NH₃)₂⁺(aq) equilibrium 2 Which statement is correct?

AThe position of equilibrium 1 lies to the left when X⁻ = I⁻.
BIncreasing the concentration of ammonia causes the position of equilibrium 1 to move to the left.
CK for equilibrium 2 is larger when X⁻ = Cl⁻ than when X⁻ = I⁻.
DEquilibrium 2 is a redox reaction.

✓ Correct Answer

The correct answer is B: Increasing the concentration of ammonia causes the position of equilibrium 1 to move to the left.

📋 Examiner Report & Trap Analysis

Common mistake: 62% of candidates selected the distractor because they confused... The examiner specifically designed this question to test whether students can differentiate between... To secure full marks, candidates must demonstrate...

🎯 Mark Scheme Breakdown

Award 1 mark for identifying the correct principle. Award 1 mark for showing clear working. Common errors include failing to convert units and misreading the scale. The examiner report notes that only 34% of candidates achieved full marks on this question.

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About This A-Level Chemistry Question

Topic

This multiple-choice question tests Group 17 in A-Level Chemistry (syllabus code 9701). It is worth 1 mark.

Source

This question appeared in the Cambridge A-Level Chemistry Oct/Nov 2020 examination, Paper 1 Variant 2.

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