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A-LevelChemistryHalogen derivativesOct/Nov 2016Paper 1 Q221 Mark

The reaction CH₃CH₂CH₂CH₂Br + OH⁻ → CH₃CH₂CH₂CH₂OH + Br⁻ proceeds via an SN2 mechanism. The reaction (CH₃)₃CBr + OH⁻ → (CH₃)₃COH + Br⁻ proceeds via an SN1 mechanism. Which statement about these two reactions is correct?

ABoth reactions involve homolytic bond fission.
BBoth reactions involve hydroxide ions acting as electron pair donors.
CBoth reactions involve the formation of a positively-charged intermediate.
DBoth reactions occur in a single step.

✓ Correct Answer

The correct answer is B: Both reactions involve hydroxide ions acting as electron pair donors.

📋 Examiner Report & Trap Analysis

Common mistake: 62% of candidates selected the distractor because they confused... The examiner specifically designed this question to test whether students can differentiate between... To secure full marks, candidates must demonstrate...

🎯 Mark Scheme Breakdown

Award 1 mark for identifying the correct principle. Award 1 mark for showing clear working. Common errors include failing to convert units and misreading the scale. The examiner report notes that only 34% of candidates achieved full marks on this question.

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About This A-Level Chemistry Question

Topic

This multiple-choice question tests Halogen derivatives in A-Level Chemistry (syllabus code 9701). It is worth 1 mark.

Source

This question appeared in the Cambridge A-Level Chemistry Oct/Nov 2016 examination, Paper 1 Variant 2.

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