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A-LevelChemistryHydroxy compounds9701/12 · Oct/Nov 2015 · Q251 Mark

Compound X has been investigated for use as an artificial sweetener. [Figure of compound X, a glucose derivative with two -Cl and multiple -OH groups] The two C-Cl bonds can be hydrolysed by hot NaOH(aq). The C-O-C bonds cannot be hydrolysed by hot NaOH(aq). What are the numbers of specified types of –OH groups before and after hydrolysing the two C-Cl bonds?

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Abefore hydrolysis: secondary: 0, primary: 1, after hydrolysis: secondary: 2, tertiary: 4
Bbefore hydrolysis: secondary: 0, primary: 2, after hydrolysis: secondary: 1, tertiary: 4
Cbefore hydrolysis: secondary: 4, primary: 1, after hydrolysis: secondary: 5, tertiary: 1
Dbefore hydrolysis: secondary: 4, primary: 2, after hydrolysis: secondary: 4, tertiary: 1

✓ Correct answer

C: before hydrolysis: secondary: 4, primary: 1, after hydrolysis: secondary: 5, tertiary: 1

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About this question

Topic
Hydroxy compounds, A-Level Chemistry (syllabus 9701). Multiple choice, 1 mark.
Source
A-Level Chemistry, Oct/Nov 2015 Paper 1 Variant 2, question 25.

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