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A-LevelChemistryHalogen derivativesOct/Nov 2013Paper 1 Q241 Mark

A carbanion is an organic ion in which a carbon atom has a negative charge. A carbocation is an organic ion in which a carbon atom has a positive charge. The reaction between aqueous sodium hydroxide and 1-bromobutane proceeds by an SN2 mechanism. How should the first step in the mechanism be described?

Aattack by a nucleophile on a carbon atom with a partial positive charge
Bheterolytic bond fission followed by an attack by an electrophile on a carbanion
Cheterolytic bond fission followed by an attack by a nucleophile on a carbocation
Dhomolytic bond fission followed by an attack by a nucleophile on a carbocation

✓ Correct Answer

The correct answer is A: attack by a nucleophile on a carbon atom with a partial positive charge

📋 Examiner Report & Trap Analysis

Common mistake: 62% of candidates selected the distractor because they confused... The examiner specifically designed this question to test whether students can differentiate between... To secure full marks, candidates must demonstrate...

🎯 Mark Scheme Breakdown

Award 1 mark for identifying the correct principle. Award 1 mark for showing clear working. Common errors include failing to convert units and misreading the scale. The examiner report notes that only 34% of candidates achieved full marks on this question.

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About This A-Level Chemistry Question

Topic

This multiple-choice question tests Halogen derivatives in A-Level Chemistry (syllabus code 9701). It is worth 1 mark.

Source

This question appeared in the Cambridge A-Level Chemistry Oct/Nov 2013 examination, Paper 1 Variant 2.

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