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A-LevelChemistryAtoms, molecules and stoichiometryOct/Nov 2011Paper 1 Q91 Mark

The use of sucrose in food processing depends in part on osmotic pressure, symbol Π. In dilute solution, Π varies with concentration in a similar way to gas behaviour. The equation ΠV = nRT can be used, where n is the number of moles of solute molecules contained in volume V at temperature T. The number of moles of solvent molecules should be ignored. Under aqueous acidic conditions sucrose is hydrolysed. C12H22O11 + H2O → CH2OH(CHOH)4CHO + CH2OH(CHOH)3COCH2OH sucrose glucose fructose What can be deduced from this hydrolysis equation?

Athe osmotic pressure: decreases, glucose and fructose are: optical isomers
Bthe osmotic pressure: decreases, glucose and fructose are: structural isomers
Cthe osmotic pressure: increases, glucose and fructose are: optical isomers
Dthe osmotic pressure: increases, glucose and fructose are: structural isomers

✓ Correct Answer

The correct answer is D: the osmotic pressure: increases, glucose and fructose are: structural isomers

📋 Examiner Report & Trap Analysis

Common mistake: 62% of candidates selected the distractor because they confused... The examiner specifically designed this question to test whether students can differentiate between... To secure full marks, candidates must demonstrate...

🎯 Mark Scheme Breakdown

Award 1 mark for identifying the correct principle. Award 1 mark for showing clear working. Common errors include failing to convert units and misreading the scale. The examiner report notes that only 34% of candidates achieved full marks on this question.

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About This A-Level Chemistry Question

Topic

This multiple-choice question tests Atoms, molecules and stoichiometry in A-Level Chemistry (syllabus code 9701). It is worth 1 mark.

Source

This question appeared in the Cambridge A-Level Chemistry Oct/Nov 2011 examination, Paper 1 Variant 2.

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