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A-LevelChemistryEquilibriaMay/June 2024Paper 5 Q215 Marks

This question is about an experiment to investigate the effect of temperature on the equilibrium constant, K₁, of the reaction shown. Fe³⁺(aq) + SCN⁻(aq) ⇌ FeSCN²⁺(aq) The data collected is used to determine the value of the enthalpy change of the reaction. To set up the equilibrium, aqueous iron(III) nitrate, Fe(NO3)3(aq), is mixed with aqueous potassium thiocyanate, KSCN(aq). Aqueous iron thiocyanate ions, FeSCN²⁺(aq), have a red colour. A colorimeter is used to measure the absorbance of the reaction mixture. A calibration graph can then be used to determine the concentration of FeSCN²⁺(aq) in the reaction mixture. [Table 2.1] shows the solutions for the experiments. Table 2.1 | solution | ion | concentration/mol dm⁻³ | |---|---|---| | A | SCN⁻(aq) | 0.00920 | | B | SCN⁻(aq) | 0.00200 | | C | Fe³⁺(aq) | 0.00200 | | D | Fe³⁺(aq) | 0.500 |

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About This A-Level Chemistry Question

This structured question appeared in the Cambridge A-Level Chemistry (9701) May/June 2024 examination, Paper 5 Variant 2. It tests the topic of Equilibria and is worth 15 marks.

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